Transient mechanics of slide-ring networks: A continuum model

نویسندگان

چکیده

Slide ring gels, developed from molecularly threaded polymer chains, have been getting increased attention for their unique modes of relaxation and toughness in the past ten years. While methods synthesis become more sophisticated efficient, theory has not kept up with experiments, there exist many unexplained observations. In this paper, we develop a continuum-level model slide gels based on thermodynamically consistent equations. We begin at level single chain perform statistical averaging to capture molecular dynamics shown by polyrotaxane, backbone network. discover dependence both strain speed deformation. explain these properties quantitatively assigning internal state variables that represent reptation relative degree chain-stretch solve evolution during

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ژورنال

عنوان ژورنال: Journal of The Mechanics and Physics of Solids

سال: 2021

ISSN: ['0022-5096', '1873-4782']

DOI: https://doi.org/10.1016/j.jmps.2020.104212